Alchemist Worldwide Ltd

Conhecimento

Material Safety Data Sheet: 2-Aminoethylamino Methyl Triethoxysilane

Identification

Product Name: 2-Aminoethylamino Methyl Triethoxysilane
Synonyms: N-(2-Aminoethyl)-3-aminopropyltrimethoxysilane, Silquest A-1120
Chemical Formula: C8H22N2O3Si
CAS Number: 1760-24-3
Recommended Use: Adhesion promoter, coupling agent in paints, coatings, sealants, and plastics
Manufacturer: [Insert company details]
Emergency Contact: [Insert emergency phone number]
Product Code: [Insert product code]

Hazard Identification

GHS Classification: Flammable liquid (Category 3), Skin irritation (Category 2), Serious eye damage (Category 1), Sensitization (Category 1), Acute toxicity oral and inhalation (Category 4)
Hazard Statements: Causes serious eye damage, causes skin irritation, may cause allergic skin reaction, harmful if inhaled or swallowed, flammable liquid and vapor
Pictograms: Flame, exclamation mark, corrosion
Signal Word: Danger
Precautionary Measures: Avoid breathing vapors, wash exposed skin thoroughly, wear protective eye and skin equipment, keep away from ignition sources, ensure good ventilation

Composition / Information on Ingredients

Chemical Name: 2-Aminoethylamino Methyl Triethoxysilane
Common Name: Silane coupling agent
CAS Number: 1760-24-3
Content: ≥95% by weight
Impurities: Water, methanol (trace amounts may evolve over time), organic solvents (traces from industrial production)
Hazardous Components: 2-Aminoethylamino Methyl Triethoxysilane is the principal hazardous ingredient and accounts for nearly all health and environmental risks noted in this document

First Aid Measures

Inhalation: Move person to fresh air immediately, keep warm and at rest, provide artificial respiration if breathing stops, seek immediate medical attention
Skin Contact: Remove contaminated clothing, rinse affected skin with water for 15 minutes or longer, seek medical advice for persistent irritation
Eye Contact: Rinse cautiously with water for at least 15 minutes, remove contact lenses if present and easy to do, continue rinsing, get urgent medical assistance
Ingestion: Do not induce vomiting, rinse mouth with water, never give anything by mouth if the person is unconscious, seek prompt medical help
Major Symptoms: Skin and eye redness, burning, severe irritation or pain, allergic reactions, headache, shortness of breath

Fire-Fighting Measures

Suitable Extinguishing Media: Alcohol-resistant foam, carbon dioxide, dry chemical powder, water fog (do not use water jet directly on substance)
Specific Hazards: Vapors may form explosive mixtures with air, containers may explode when hot, may emit toxic fumes of nitrogen oxides and silicon oxides
Protective Equipment for Firefighters: Wear full turnout gear, including self-contained breathing apparatus, chemical-resistant gloves and boots
Special Procedures: Cool containers with water spray to prevent pressure buildup, remain upwind, prevent runoff from entry into waterways
Advice: Recognize that fire will produce intense heat and dangerous gases; evacuation of the area and use of remote firefighting techniques may be required

Accidental Release Measures

Personal Precautions: Evacuate unnecessary personnel, wear respiratory protection, use chemical-resistant gloves, safety goggles, avoid contact with skin and eyes, ventilate area
Environmental Precautions: Prevent further leakage or spillage, avoid entry to drains, sewers, waterways, inform authorities if significant contamination occurs
Clean-Up Methods: Absorb with sand, earth, or inert absorbent, place into closed chemical waste containers, wash spill site after material pickup, ventilate contaminated area
Special Instructions: Use spark-proof tools, avoid generating aerosols, dispose of all cleanup materials in accordance with local and national regulations, decontaminate all personnel and equipment exposed to spilled material

Handling and Storage

Safe Handling: Work in a chemical fume hood or well-ventilated space, wear protective clothing, keep away from heat, sparks, open flames, do not breathe vapors, avoid contact with skin, eyes, clothing
Conditions for Safe Storage: Store in tightly closed, clearly labeled containers, keep container in a cool, dry, well-ventilated place, separate from acids, oxidizers, and incompatible chemicals
Storage Temperatures: Preferably below 25°C (77°F)
Incompatible Materials: Strong acids, bases, oxidizing agents, moisture
Advice on Storage Stability: Regularly check containers for signs of leaks, product may slowly hydrolyze releasing ethanol, handle opened containers with care to avoid air and moisture contamination

Exposure Controls and Personal Protection

Exposure Limits: No occupational exposure limit assigned by OSHA or ACGIH, treat as hazardous based on toxic effects
Engineering Controls: Use chemical fume hood, explosion-proof ventilation, eyewash and safety shower stations nearby
Personal Protective Equipment: Chemical-resistant gloves (nitrile or neoprene), splash goggles, face shield, lab coat or impervious apron, long sleeves and pants, closed-toe shoes
Respiratory Protection: Use a NIOSH-approved organic vapor respirator in case of insufficient ventilation or aerosol risk
Hygiene Measures: Wash hands and exposed skin after handling, do not eat, drink, or smoke around product, regularly clean work surfaces

Physical and Chemical Properties

Appearance: Colorless to pale yellow transparent liquid
Odor: Ammonia-like odor
Odor Threshold: Not determined
pH: Not available
Melting Point: No data (liquid at room temperature)
Boiling Point: Approx. 238°C (460°F)
Flash Point: Approx. 110°C (230°F) (closed cup)
Evaporation Rate: Not established
Flammability: Burns with difficulty but vapor may ignite
Explosion Limits: Lower: not determined, Upper: not determined
Vapor Pressure: Low at 20°C
Vapor Density: Heavier than air
Density: 0.98–1.02 g/cm³ at 20°C
Solubility: Hydrolyzes in water, soluble in alcohols and ketones
Partition Coefficient (log Pow): No data available
Auto-Ignition Temperature: Over 250°C (482°F)
Decomposition Temperature: Not determined
Viscosity: Approx. 2 mPa.s at 25°C

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions, sensitive to moisture, product slowly hydrolyzes releasing ethanol
Conditions to Avoid: Avoid contact with water or moisture, heat, sources of ignition, direct sunlight
Materials to Avoid: Acids, bases, oxidizing agents, water
Hazardous Decomposition Products: Carbon oxides, silicon oxides, nitrogen oxides, ethyleneimine (trace, under harsh conditions), ethanol
Polymerization: Does not readily polymerize under normal conditions but can form gels with water
Other Reactivity Risks: Prolonged contact with air or water promotes decomposition and loss of effectiveness

Toxicological Information

Acute Toxicity: May cause severe irritation, burns to skin and eyes, ingestion or inhalation can be harmful, LD50 (Oral, rat): approx. 1780 mg/kg, LD50 (Dermal, rabbit): >2000 mg/kg
Skin Corrosion/Irritation: Causes moderate to severe irritation and sensitives in some individuals
Eye Damage/Irritation: Severe and potentially irreversible eye damage
Respiratory Sensitization: Repeated exposure to vapors can cause allergic respiratory symptoms
Chronic Effects: May cause dermatitis, prolonged or repeated exposure has potential for sensitization
Carcinogenicity: Not listed as a carcinogen by IARC, NTP, or OSHA
Mutagenicity: No evidence of mutagenic potential based on available studies
Reproductive Toxicity: No available human data on reproductive effects

Ecological Information

Eco-Toxicity: Toxic to aquatic life based on structure and similar compounds, may cause long-term adverse effects in the aquatic environment
Persistence and Degradability: Slowly hydrolyzes in water to produce siloxanes and ethanol, non-biodegradable under natural environmental conditions
Bioaccumulation Potential: Not expected to bioaccumulate significantly
Mobility in Soil: Limited mobility, binds to soil and sediments over time
Additional Notes: Spillage or wash water should not enter drains, sewers, or natural water bodies

Disposal Considerations

Disposal Methods: Dispose of in accordance with federal, state, and local regulations as hazardous waste, use licensed chemical disposal contractor
Container Disposal: Do not puncture or incinerate even when empty, triple rinse containers, offer rinsing residues to hazardous waste treatment plants
Special Instructions: Avoid release to the environment, do not dump into waterways, inform local waste authorities if unsure about proper disposal

Transport Information

UN Number: UN1993
Proper Shipping Name: Flammable Liquid, N.O.S. (2-Aminoethylamino Methyl Triethoxysilane)
Transport Hazard Class: 3 (Flammable liquids)
Packing Group: III
Labels: Flammable Liquid Symbol
Special Provisions: Keep away from heat and open flames during transport, protect from physical damage, ensure upright transport
Marine Pollutant: Not identified as a marine pollutant in typical concentrations
Emergency Procedures: Refer to the U.S. DOT Emergency Response Guidebook for appropriate actions in case of spillage or accidental release during transit

Regulatory Information

U.S. Regulations: Subject to OSHA Hazard Communication Standard, listed on TSCA inventory, SARA 302/304: No, SARA 311/312: Yes (hazardous chemical), SARA 313: No reportable ingredients
EC Regulations: Listed in EINECS (EC Number: 217-164-6), subject to REACH registration, requires hazard labeling under CLP Regulation
Canada: Listed on DSL, regulated under WHMIS with flammable, toxic, irritant classifications
Other Global Regulations: Listed or notified in Australia, New Zealand, Japan, Korea, and China chemical inventories
Workplace Control: Requires safety data sheet access and hazard training for employees, enforce strict adherence to workplace exposure limits and personal protection