Product Name: 2-Aminoethylamino Methyl Triethoxysilane
Synonyms: N-(2-Aminoethyl)-3-aminopropyltrimethoxysilane, Silquest A-1120
Chemical Formula: C8H22N2O3Si
CAS Number: 1760-24-3
Recommended Use: Adhesion promoter, coupling agent in paints, coatings, sealants, and plastics
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GHS Classification: Flammable liquid (Category 3), Skin irritation (Category 2), Serious eye damage (Category 1), Sensitization (Category 1), Acute toxicity oral and inhalation (Category 4)
Hazard Statements: Causes serious eye damage, causes skin irritation, may cause allergic skin reaction, harmful if inhaled or swallowed, flammable liquid and vapor
Pictograms: Flame, exclamation mark, corrosion
Signal Word: Danger
Precautionary Measures: Avoid breathing vapors, wash exposed skin thoroughly, wear protective eye and skin equipment, keep away from ignition sources, ensure good ventilation
Chemical Name: 2-Aminoethylamino Methyl Triethoxysilane
Common Name: Silane coupling agent
CAS Number: 1760-24-3
Content: ≥95% by weight
Impurities: Water, methanol (trace amounts may evolve over time), organic solvents (traces from industrial production)
Hazardous Components: 2-Aminoethylamino Methyl Triethoxysilane is the principal hazardous ingredient and accounts for nearly all health and environmental risks noted in this document
Inhalation: Move person to fresh air immediately, keep warm and at rest, provide artificial respiration if breathing stops, seek immediate medical attention
Skin Contact: Remove contaminated clothing, rinse affected skin with water for 15 minutes or longer, seek medical advice for persistent irritation
Eye Contact: Rinse cautiously with water for at least 15 minutes, remove contact lenses if present and easy to do, continue rinsing, get urgent medical assistance
Ingestion: Do not induce vomiting, rinse mouth with water, never give anything by mouth if the person is unconscious, seek prompt medical help
Major Symptoms: Skin and eye redness, burning, severe irritation or pain, allergic reactions, headache, shortness of breath
Suitable Extinguishing Media: Alcohol-resistant foam, carbon dioxide, dry chemical powder, water fog (do not use water jet directly on substance)
Specific Hazards: Vapors may form explosive mixtures with air, containers may explode when hot, may emit toxic fumes of nitrogen oxides and silicon oxides
Protective Equipment for Firefighters: Wear full turnout gear, including self-contained breathing apparatus, chemical-resistant gloves and boots
Special Procedures: Cool containers with water spray to prevent pressure buildup, remain upwind, prevent runoff from entry into waterways
Advice: Recognize that fire will produce intense heat and dangerous gases; evacuation of the area and use of remote firefighting techniques may be required
Personal Precautions: Evacuate unnecessary personnel, wear respiratory protection, use chemical-resistant gloves, safety goggles, avoid contact with skin and eyes, ventilate area
Environmental Precautions: Prevent further leakage or spillage, avoid entry to drains, sewers, waterways, inform authorities if significant contamination occurs
Clean-Up Methods: Absorb with sand, earth, or inert absorbent, place into closed chemical waste containers, wash spill site after material pickup, ventilate contaminated area
Special Instructions: Use spark-proof tools, avoid generating aerosols, dispose of all cleanup materials in accordance with local and national regulations, decontaminate all personnel and equipment exposed to spilled material
Safe Handling: Work in a chemical fume hood or well-ventilated space, wear protective clothing, keep away from heat, sparks, open flames, do not breathe vapors, avoid contact with skin, eyes, clothing
Conditions for Safe Storage: Store in tightly closed, clearly labeled containers, keep container in a cool, dry, well-ventilated place, separate from acids, oxidizers, and incompatible chemicals
Storage Temperatures: Preferably below 25°C (77°F)
Incompatible Materials: Strong acids, bases, oxidizing agents, moisture
Advice on Storage Stability: Regularly check containers for signs of leaks, product may slowly hydrolyze releasing ethanol, handle opened containers with care to avoid air and moisture contamination
Exposure Limits: No occupational exposure limit assigned by OSHA or ACGIH, treat as hazardous based on toxic effects
Engineering Controls: Use chemical fume hood, explosion-proof ventilation, eyewash and safety shower stations nearby
Personal Protective Equipment: Chemical-resistant gloves (nitrile or neoprene), splash goggles, face shield, lab coat or impervious apron, long sleeves and pants, closed-toe shoes
Respiratory Protection: Use a NIOSH-approved organic vapor respirator in case of insufficient ventilation or aerosol risk
Hygiene Measures: Wash hands and exposed skin after handling, do not eat, drink, or smoke around product, regularly clean work surfaces
Appearance: Colorless to pale yellow transparent liquid
Odor: Ammonia-like odor
Odor Threshold: Not determined
pH: Not available
Melting Point: No data (liquid at room temperature)
Boiling Point: Approx. 238°C (460°F)
Flash Point: Approx. 110°C (230°F) (closed cup)
Evaporation Rate: Not established
Flammability: Burns with difficulty but vapor may ignite
Explosion Limits: Lower: not determined, Upper: not determined
Vapor Pressure: Low at 20°C
Vapor Density: Heavier than air
Density: 0.98–1.02 g/cm³ at 20°C
Solubility: Hydrolyzes in water, soluble in alcohols and ketones
Partition Coefficient (log Pow): No data available
Auto-Ignition Temperature: Over 250°C (482°F)
Decomposition Temperature: Not determined
Viscosity: Approx. 2 mPa.s at 25°C
Chemical Stability: Stable under recommended storage conditions, sensitive to moisture, product slowly hydrolyzes releasing ethanol
Conditions to Avoid: Avoid contact with water or moisture, heat, sources of ignition, direct sunlight
Materials to Avoid: Acids, bases, oxidizing agents, water
Hazardous Decomposition Products: Carbon oxides, silicon oxides, nitrogen oxides, ethyleneimine (trace, under harsh conditions), ethanol
Polymerization: Does not readily polymerize under normal conditions but can form gels with water
Other Reactivity Risks: Prolonged contact with air or water promotes decomposition and loss of effectiveness
Acute Toxicity: May cause severe irritation, burns to skin and eyes, ingestion or inhalation can be harmful, LD50 (Oral, rat): approx. 1780 mg/kg, LD50 (Dermal, rabbit): >2000 mg/kg
Skin Corrosion/Irritation: Causes moderate to severe irritation and sensitives in some individuals
Eye Damage/Irritation: Severe and potentially irreversible eye damage
Respiratory Sensitization: Repeated exposure to vapors can cause allergic respiratory symptoms
Chronic Effects: May cause dermatitis, prolonged or repeated exposure has potential for sensitization
Carcinogenicity: Not listed as a carcinogen by IARC, NTP, or OSHA
Mutagenicity: No evidence of mutagenic potential based on available studies
Reproductive Toxicity: No available human data on reproductive effects
Eco-Toxicity: Toxic to aquatic life based on structure and similar compounds, may cause long-term adverse effects in the aquatic environment
Persistence and Degradability: Slowly hydrolyzes in water to produce siloxanes and ethanol, non-biodegradable under natural environmental conditions
Bioaccumulation Potential: Not expected to bioaccumulate significantly
Mobility in Soil: Limited mobility, binds to soil and sediments over time
Additional Notes: Spillage or wash water should not enter drains, sewers, or natural water bodies
Disposal Methods: Dispose of in accordance with federal, state, and local regulations as hazardous waste, use licensed chemical disposal contractor
Container Disposal: Do not puncture or incinerate even when empty, triple rinse containers, offer rinsing residues to hazardous waste treatment plants
Special Instructions: Avoid release to the environment, do not dump into waterways, inform local waste authorities if unsure about proper disposal
UN Number: UN1993
Proper Shipping Name: Flammable Liquid, N.O.S. (2-Aminoethylamino Methyl Triethoxysilane)
Transport Hazard Class: 3 (Flammable liquids)
Packing Group: III
Labels: Flammable Liquid Symbol
Special Provisions: Keep away from heat and open flames during transport, protect from physical damage, ensure upright transport
Marine Pollutant: Not identified as a marine pollutant in typical concentrations
Emergency Procedures: Refer to the U.S. DOT Emergency Response Guidebook for appropriate actions in case of spillage or accidental release during transit
U.S. Regulations: Subject to OSHA Hazard Communication Standard, listed on TSCA inventory, SARA 302/304: No, SARA 311/312: Yes (hazardous chemical), SARA 313: No reportable ingredients
EC Regulations: Listed in EINECS (EC Number: 217-164-6), subject to REACH registration, requires hazard labeling under CLP Regulation
Canada: Listed on DSL, regulated under WHMIS with flammable, toxic, irritant classifications
Other Global Regulations: Listed or notified in Australia, New Zealand, Japan, Korea, and China chemical inventories
Workplace Control: Requires safety data sheet access and hazard training for employees, enforce strict adherence to workplace exposure limits and personal protection