Alchemist Worldwide Ltd

Conhecimento

MSDS for 3-(N-Cyclohexylamino)Propylmethyldimethoxy Silane

Identification

Product Name: 3-(N-Cyclohexylamino)Propylmethyldimethoxy Silane
Chemical Family: Alkoxysilane
Recommended Uses: Surface treatment agent, adhesion promoter, coupling agent
Supplier: Manufacturer or distributor, including address and emergency contact number
CAS Number: 3068-78-8
SDS Number: Unique identifier assigned by supplier
Emergency Telephone Number: Local or international poison center contact

Hazard Identification

Classification (GHS): Flammable liquids, skin irritation, serious eye damage/irritation, specific target organ toxicity
Signal Word: Warning
Hazard Statements: Causes skin and eye irritation, flammable liquid and vapor, may cause respiratory irritation, possible long-term effects if inhaled
Pictograms: Flame, exclamation mark
Precautionary Statements: Keep away from heat, use personal protective gear, avoid contact or inhalation, use only outdoors or in a well-ventilated area
Other Hazards: May form hazardous decomposition products under fire conditions, vapor heavier than air

Composition / Information on Ingredients

Chemical Name: 3-(N-Cyclohexylamino)Propylmethyldimethoxy Silane
Chemical Formula: C12H27NO2Si
Synonyms: Cyclohexylaminopropylmethyldimethoxysilane
CAS Number: 3068-78-8
Impurities and Stabilizing Additives: Trace residual organic solvents or by-products below reportable thresholds
Concentration: 95% or higher (balance may include proprietary solvents or carriers)

First Aid Measures

Eye Contact: Rinse carefully and thoroughly with water for 15 minutes, lift eyelids for complete irrigation, seek medical help promptly if irritation persists
Skin Contact: Remove contaminated clothing, wash exposed skin with soap and water, seek medical advice if symptoms occur, wash clothing before reuse
Inhalation: Move affected person to fresh air, maintain open airway and provide oxygen if breathing feels difficult, seek immediate medical attention if symptoms do not subside
Ingestion: Rinse mouth, do not induce vomiting unless instructed by medical personnel, seek prompt medical attention
Most Important Symptoms: Redness, skin or mucous membrane irritation, headache, dizziness or coughing
Immediate Medical Attention: Necessary if breathing difficulty or persistent eye/skin irritation occurs

Fire-Fighting Measures

Suitable Extinguishing Media: Use alcohol-resistant foam, dry chemical, carbon dioxide, or water spray
Unsuitable Extinguishing Media: High-pressure water streams might scatter flammable liquid
Specific Hazards During Fire: Vapors may form explosive mixtures with air; combustion yields carbon oxides, nitrogen oxides, silicon oxides, toxic fumes
Protective Equipment for Firefighters: Full protective clothing, self-contained breathing apparatus
Special Fire-Fighting Procedures: Evacuate downwind areas, use water spray to cool exposed containers, contain runoff
Additional Advice: Avoid inhaling smoke or combustion products

Accidental Release Measures

Personal Precautions: Evacuate unprotected personnel from area, ventilate the area, avoid breathing vapors, wear appropriate personal protection (see Exposure Controls)
Environmental Precautions: Prevent further leakage, avoid discharge into soil, sewers, or natural water bodies
Containment Methods: Contain spill with inert, non-combustible absorbent material (sand, diatomaceous earth), transfer to properly-labelled waste container
Clean-Up Procedures: Sweep up carefully, collect spilled material, dispose of in accordance with regulations
Decontamination: Wash area with water to remove residues, avoid creating dust or aerosols

Handling and Storage

Precautions for Safe Handling: Wear chemical resistant gloves and goggles, work in well-ventilated space, avoid contact with skin, eyes, clothing, keep away from ignition sources, do not breathe vapors or mist, wash hands after handling
Conditions for Safe Storage: Store in tightly closed, original container, in cool, dry, and well-ventilated area, keep away from direct sunlight, heat, oxidizers, acids, and moisture; inert gas blanketing recommended if available
Incompatibilities: Strong oxidizing agents, strong acids, water (hydrolysis may occur upon contact)
Storage Temperature: Keep below 40°C/104°F if possible
Other Storage Protocols: Clear labelling of containers, secure against overturning, secondary containment as required for flammable liquids

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established limit for this compound; maintain levels as low as possible
Engineering Controls: Use local exhaust ventilation, fume hoods, explosion-proof electrical equipment
Personal Protective Equipment: Chemical splash goggles, gloves impervious to chemicals, flame-resistant lab coats, chemical-resistant apron, properly fitted respirator if vapor concentrations are high
Hygiene Measures: Wash hands and face after handling, remove contaminated clothing and wash before reuse, do not eat, drink, or smoke in workplace
Environmental Precautions: Avoid release to sewage or surface water, ensure adequate engineering controls to prevent environmental contamination

Physical and Chemical Properties

Appearance: Clear to pale yellow liquid
Odor: Characteristic amine-like
Odor Threshold: Not established
pH: Not measured in water
Melting Point/Freezing Point: -60°C to -50°C
Boiling Point/Range: 110°C to 120°C at 1 atm
Flash Point: 62°C (closed cup, approximate)
Evaporation Rate: Slower compared to ether; actual value not determined
Flammability: Liquid, flammable above flash point
Upper/Lower Flammability Limits: Lower: 1.1% / Upper: 6.0% (estimated)
Vapor Pressure: 4 mmHg at 25°C
Vapor Density: Heavier than air
Relative Density: 0.97 - 1.02 g/cm³
Solubility: Hydrolizes in water, limited solubility, miscible with organic solvents
Partition Coefficient (n-octanol/water): Not available
Self-Ignition Temperature: 255°C
Decomposition Temperature: >200°C
Viscosity: 1-3 mPa·s

Stability and Reactivity

Chemical Stability: Stable under recommended conditions, reacts slowly with water and moist air
Possibility of Hazardous Reactions: Contact with strong oxidants, acids, or bases accelerates decomposition; hydrolyzes forming methanol, may release flammable or toxic gases in fire
Conditions to Avoid: Excess moisture, sources of ignition, extreme heat, incompatible chemicals
Incompatible Materials: Oxidizing agents, strong acids, moisture, strong bases
Hazardous Decomposition Products: Methanol, cyclohexylamine, nitrogen oxides, siloxanes, carbon monoxide, carbon dioxide

Toxicological Information

Acute Toxicity: Oral LD50 (rat): estimated 500-2000 mg/kg, inhalation or dermal data not specifically reported
Skin Corrosion/Irritation: Causes skin irritation, repeated or long-term contact may lead to dermatitis
Serious Eye Damage/Irritation: Can result in serious eye irritation, possible corneal injury
Respiratory or Skin Sensitization: Not classified as sensitizer, may cause irritation
Germ Cell Mutagenicity: No data to suggest mutagenic potential
Carcinogenicity: No evidence in animal studies
Reproductive Toxicity: Not classified as toxic to reproduction
Specific Target Organ Toxicity (Single/Repeated Exposure): May cause respiratory tract irritation
Aspiration Hazard: Not classified, but viscosity and volatility suggest possible aspiration risk if ingested
Other Effects: Prolonged or repeated exposure may cause effects to liver, kidneys, or central nervous system

Ecological Information

Ecotoxicity: Limited acute aquatic toxicity data; hydrolysis products may pose risk to aquatic organisms; methanol and siloxanes may affect water organisms
Persistence and Degradability: Hydrolyzes in water over time, primary decomposition yields methanol and aminoalkyl silanes which are biodegradable under aerobic conditions
Bioaccumulative Potential: Not expected to bioaccumulate; hydrolysis products have moderate bioaccumulation risk
Mobility in Soil: Hydrolyzes to less mobile silanols, methanol is highly mobile
Results of PBT and vPvB Assessment: Not expected to be persistent, bioaccumulative, or toxic
Other Adverse Effects: Discharge to water can harm aquatic life; always avoid uncontrolled releases

Disposal Considerations

Waste Treatment Methods: Dispose in accordance with local, national, and international regulations, incineration in equipped facility preferred
Contaminated Packaging: Empty containers may pose hazard, triple rinse or use industrial incineration for disposal
Special Precautions for Disposal: Avoid release to environment, label waste containers clearly, do not reuse empty drums, keep waste separated from incompatible materials
Disposal of Hydrolysis Byproducts: Handle methanol and silanol residues as hazardous waste

Transport Information

UN Number: UN 1993
UN Proper Shipping Name: Flammable Liquid, n.o.s. (3-(N-Cyclohexylamino)Propylmethyldimethoxy Silane mixture)
Transport Hazard Class: 3 (Flammable Liquids)
Packing Group: III, moderate hazard
Marine Pollutant: Not classified as marine pollutant under IMDG
Special Precautions for Transport: Keep containers upright, properly labelled, segregate from food and incompatible materials
Transport in Bulk: Only in approved tank cars or drums, ensure final destination has adequate facilities for safe unloading and handling
Additional Notes: Follow local and international transport legislation

Regulatory Information

EU REACH Status: Substance registered or pre-registered, subject to safety data requirements
OSHA (US): Not specifically regulated, general chemical safety standards apply
TSCA (US): Listed in TSCA Inventory
WHMIS (Canada): Class B2: Flammable liquid, Class D2B: Toxic material causing other toxic effects
DSL/NDSL (Canada): Listed
SARA Title III: Not specifically listed as an extremely hazardous substance
California Proposition 65: Contains no known components required for Prop 65 labelling
Other International Inventory Lists: Australia (AICS): Listed; Japan (ENCS): Listed; Korea (KECI): Listed; China (IECSC): Listed
Other Applicable Regulations: Observe all national, local, and international chemical regulations and workplace safety laws