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Mixture of Bis[3-(Triethoxysilyl)Propyl]Disulfide and Carbon Black: A Close Look

Historical Development

Curiosity drives plenty of chemical breakthroughs. That’s exactly how Bis[3-(Triethoxysilyl)propyl]disulfide wandered from the pages of organic chemistry books into practical compounds found throughout industrial processes. In the early days, companies set out to make rubber stronger. Standard sulfur cures worked but lacked finesse, especially in the chase for better tires and durable components. Someone realized mixing a silane coupling agent like this with carbon black could push performance farther, right down at the contact point between rubber, filler, and silanol surfaces inside composites. Carbon black brought reinforcing strength, but silanes built the chemical bridges, creating more than the sum of the pieces. These developments did not happen overnight—mid-century research papers and patent races by European and American giants shaped the mixtures hitting the market today.

Product Overview

Seeing Bis[3-(Triethoxysilyl)propyl]disulfide paired with carbon black at a fifty-fifty split puts technical goals front and center. Individually, Bis[3-(Triethoxysilyl)propyl]disulfide works as a silane coupling agent, a go-between that latches rubber to minerals or blacks. Carbon black by itself gives black pigment, abrasion resistance, tensile strength, and toughness to rubber goods. Mix them, and you tap into synergistic effects: more efficient cross-linking during vulcanization, better filler dispersion, fewer waste particles, and rubber that stands up to harsh environments. Instead of an off-the-shelf solution, it’s more like a toolkit built for engineers and researchers who want to squeeze every bit of performance out of filled polymers.

Physical & Chemical Properties

This hybrid blend forms a free-flowing, dark, gritty powder. The carbon black swallows light, gives it bulk, and delivers low electrical conductivity. The silane brings a faint mercaptan odor, slight stickiness when humid, and some hydrolytic reactivity—especially if storage skips on sealing or humidity controls. Real-world labs report a density near 1.7 to 1.9 g/cm³, with a relatively wide surface area range, depending on the carbon black’s pore structure. Solubility runs low in water but rises in certain organics, and the chemical bond between disulfide groups and silica surfaces offers a deep toolbox for process chemists.

Technical Specifications & Labeling

Manufacturers need to slap down clear details. Content splits precisely at 50% for each component, but specifications stretch far: sieve residue, ignition residue, silane purity, moisture content, ash percentage, and pH, all get a line item. Reliable suppliers include batch numbers, storage guidelines, and shelf life on every drum or bag. Industry standards—such as ASTM and ISO labeling—spell out hazards, lot traceability, and recommended protective measures, right down to the smallest font on a data sheet.

Preparation Method

Crafting this mixture doesn’t stop at dumping powders into a barrel. Production teams blend Bis[3-(Triethoxysilyl)propyl]disulfide into carbon black using ribbon blenders or high-shear mixers under a dry nitrogen or inert atmosphere. This keeps both oxidation and static risk under control. Careful addition helps each silane droplet coat the black’s microscopic surface, guarding against clumping. In my mix room days, skipping the slow, even addition led to lumpy batches—impossible to handle during downstream processing.

Chemical Reactions & Modifications

Inside rubber compounding, the disulfide bond opens pathways for sulfur cross-linking. It anchors onto silica or hydroxyl groups, especially during mixing at tire factories, producing covalent silicon-oxygen bridges. Even minor shifts in batch composition or curing temperature kick off different levels of cross-link density, shifting tensile strength and abrasion resistance. Some research teams swap out the ethoxy groups for methoxy or other silanes to tune coupling strength or hydrolysis rates—always itching for a better balance between processability and physical properties.

Synonyms & Product Names

Depending on the supplier or application, you might see longer chemical names, acronyms like TESPD, or trade names slapped on the bag by major chemical houses. In rubber industry slang, folks sometimes call it “silane-modified carbon black,” though formal documentation avoids loose wording for regulatory reasons.

Safety & Operational Standards

Mixing and handling these powders puts operator safety in the spotlight. The silane’s volatile organic content, sharp odor, and potential for irritation means PPE is non-negotiable: respirators, goggles, double gloves, and proper ventilation go into every risk assessment. Warehouses I’ve seen keep inventory far from open flames and control static electricity, given the carbon black’s fine particle size and combustibility history. Manufacturers run regular workplace monitoring for dust levels, updating safety data sheets every few years as new research shapes global chemical safety rules.

Application Area

Most of the real action happens in the tire and technical rubber sector, where this chemistry delivers higher performance tread compounds, treads that bite wet pavement, and seals that shrug off heat, UV, and aggressive chemicals. Beyond tires, this blend also turns up in conveyor belts, hoses, shoe soles, and vibration isolators for heavy industry. Over in R&D, folks chase new corners: conductive rubber for electronics, improved energy efficiency in electric vehicles, rubber-particle composites that last longer in food contact or biomedical applications. Every industry chasing elasticity, wear resistance, and chemical resilience pays attention.

Research & Development

University groups and corporate labs continue to pick apart every step of the silane–carbon black relationship. Journals overflow with talks of filler–polymer interactions, new spectroscopies showing how silanes change surface chemistry at atomic scales, and long-term aging studies for rubbers with or without these coupling agents. Even marginal shifts in ratios seem to make or break a new tread formula. Conferences get crowded with talks about greener, safer silanes, or more sustainable sources for fillers, as regulatory pressure grows worldwide.

Toxicity Research

Safety studies focus both on acute exposure—how much irritation or sensitization workers face—and on longer-term risks. I’ve read animal studies raising few red flags at ordinary workplace levels, but data gaps persist across chronic, low-dose exposure and combined effects with common vulcanization agents. Regulators in Europe and North America keep tabs on occupational exposure, setting threshold limits for airborne carbon black, and call for ongoing medical monitoring. Labs still check old silane samples for byproduct formation and systemic toxicity, especially as new uses for these blends grow outside traditional tire plants.

Future Prospects

This chemical couple keeps drawing investment for good reason. Engineers want higher fuel economy from lower-rolling-resistance tires—something this mixture supports by cutting energy loss inside the compound. Newer blends combine different silanes or tailor particle surfaces for smart sensors, energy storage, and lightweight structural parts. Companies eyeing the electric vehicle boom see room for breakthroughs as heat aging and conductivity demands climb. Plus, strong eco-friendly trends keep pushing research on renewable raw materials and safer, lower-emission mixes. Count on the next decade to bring smarter formulations and tighter controls, shaped by relentless demand for performance—without sacrificing workplace or environmental safety.




What are the main applications of Mixture Of Bis[3-(Triethoxysilyl)Propyl]Disulfide (50%) And Carbon Black (50%)?

The Science People Count On—Without Realizing It

Look at any modern tire. Chances are high that a good chunk of what holds it together comes from a blend of two materials: Bis[3-(Triethoxysilyl)Propyl]Disulfide and carbon black. Tire engineers have aimed for decades to balance longer tread life, better grip in the rain, and low rolling resistance to save fuel. This pairing in the material mix helped break new ground, giving tires better durability and easier handling.

Long Drives and Safe Braking—Why This Mix Matters

Mix Bis[3-(Triethoxysilyl)Propyl]Disulfide with carbon black and rubber becomes more than just stretchy; it grabs onto the road. The silane acts like a bridge, helping the rubber bond to the black particles. That extra chemistry means a tire can handle heat, flex under weight, and come back strong after hitting thousands of potholes. Studies from the past ten years show that tires built with these materials keep their wet traction longer, cutting down stopping distances on slick asphalt.

Beyond the Road—Factories Keep Leaning on This Blend

Conveyor belts, shoe soles, seals for plumbing, and vibration pads in washing machines—they all benefit from the durability this combo brings. Factory owners have told me keeping machines up and running means fewer breakdowns; the more reliable the seals and belts inside production lines, the fewer emergency repairs. It’s not only about tire shops. Where constant friction and bending threaten to crack rubber, the robust link between silane and carbon black stands guard.

Sustainability and Waste Reduction—A Real Prize

Longer-lasting products mean less scrap rubber heading to landfills. According to data from the U.S. Tire Manufacturers Association, tire longevity increased by over 30% since the rise of these advanced mixes. I’ve seen auto shops commend manufacturers for making products that stand up to harsher climates. Farmers using tractors on rough terrain can stretch the lifespan of their equipment—saving money and reducing waste at the same time.

Room for Progress—Greener Chemistry

Environmental experts call for less dependence on petroleum feedstocks. Some companies are already testing plant-based alternatives for rubber, but the core silane–carbon black system isn’t easy to replace. Researchers at universities in Germany and Japan are tweaking silane chemistry to lower volatile organic compound emissions during mixing and curing. I remember talking with a chemist who joked that the best rubber chemists are always searching for fewer fumes and less waste, even if the current system works well today.

Making the Chemistry Safer at Work

No industrial process is risk-free. Handling silanes and carbon black powders can affect workers if they breathe dust or vapors. Factories upgraded their air systems, hoping to protect their teams. Overseas, regulations tighten each year. Protecting hands, lungs, and eyes in actual workshops keeps skilled folks on the job—a lesson learned after decades of trial and error.

Where to Next?

This chemical pairing shaped how people drive, build, and fix things every day. The push for safer, more durable products keeps driving research. As I see it, marrying deep chemistry know-how with healthier, more stable factory jobs stands as the next big milestone. The backbone of good tires and long-lasting seals starts with this mix—and the team behind it always looks for the next improvement.

What safety precautions should be taken when handling this product?

Understanding the Risks

Every time I pick up a chemical product at work or home, I check the label for hazard symbols. My hands act on habit, but the brain needs a reminder: gloves, goggles, and a well-ventilated area save more than just skin and lungs. Specific hazards jump out—irritant, flammable, corrosive, toxic. Each symbol points toward a different story of accidents, and too many people skip simple steps because they want to get the job done faster.

Personal Protective Equipment Matters

I learned early on that cotton gloves don’t cut it for strong acids or solvents. Thick nitrile or neoprene gloves keep harsh liquids from reaching skin. For dusty powders, large goggles prevent fine particles from getting into my eyes. An N95 mask or a full respirator helps a lot if the label warns about inhalation risks. In hot weather, these layers feel uncomfortable, but I’ve seen what chemical burns look like, so I keep them on until the product’s packed away.

Safe Spaces Make the Difference

Ventilation makes all the difference. I keep windows open and turn on extraction fans whenever a product gives off fumes. Basements and small sheds trap vapors where they cause headaches or worse. Outdoors is best, though wind can carry sprays right back at you. Pouring or mixing chemicals in a bathtub or near food sets everyone up for trouble down the line.

Reading the Fine Print Saves Health

Instructions hide details people miss. Recently, a friend shrugged at a warning to avoid mixing bleach with ammonia. A few breaths of that cloud sent him to the ER. Manufacturers include these lines because they’ve gone through lab accidents, injury reports, and testing. Skipping the steps gives bad results, and the cost can mean a doctor’s bill or a burned countertop. I keep the original container handy till everything’s used up, so I never lose track of the safety facts.

Storing Products the Right Way

I lost a shelf of household chemicals once by stuffing them together under the sink. Strong cleaners split their bottles and mixed onto the floor. Corrosives need their own shelf, far from anything flammable or reactive. Heavy containers go low, never above your head. Labels need to face out, so there’s no guessing in the dark. Every time a lid cracks or seal breaks, I reinforce it with fresh tape or swap bottles. Consistent storage keeps children, pets, and even adults safe.

Smart Disposal

Once a product’s past its use, disposal matters as much as storage. Dumping leftover paint or pesticides in the sink creates problems for water supplies and wildlife. Municipal disposal sites or hazardous waste pickups exist for this reason, though it sometimes takes a drive to get there. A little effort avoids long-term messes for others to clean up.

Everyday Habits Prevent Big Accidents

These habits stick around because the results of skipping them linger much longer. Emergency rooms fill up with burns, lung injuries, and poisoning cases that trace back to a forgotten glove or missed instruction. Safety routines shape outcomes, whether you work in a lab or scrub your bathroom floor. I find routine and clear label reading prevent almost every story that ends with someone regretting their shortcuts.

How should the mixture be stored to maintain stability and quality?

Real Reasons Storage Matters

I’ve seen more than a few batches go bad because someone ignored good storage. Mixtures aren’t always as stable as we’d like them to be. Left in the wrong spot, they clump, settle, or lose their punch. Temperature, light, air, and even the material of the container—these all affect how long a mixture stays at its best.

Temperature: The Silent Spoiler

High heat speeds up chemical reactions and invites spoilage. If a mixture stands in a warm place, it can oxidize or break down faster. Cold can work against us, too. Ever seen sugar-based blends get rock-hard in cold weather? The sweet spot tends to lie in cool, steady temperatures. The U.S. Pharmacopeia, for example, recommends a storage range of 15°C to 25°C for most pharmaceutical blends. That’s a clear, practical range to shoot for in almost any setting—from the lab to the kitchen.

Light: More Than Just Illumination

Exposure to sunlight seems harmless, but it leads to fading, moisture buildup, or even changes in texture and taste, especially in natural or sensitive ingredients. I recall watching spices near a south-facing window lose their color and aroma months before their expected date—no unusual "processing" needed. Opaque containers or storage away from direct light saves a lot of money and headaches.

Air and Moisture: Friends of Spoilage

Once a mixture pulls in moisture or oxygen, microbial growth picks up. Those with organic ingredients—think herbal blends or dough starters—risk mold if not sealed tight. Oxygen also pushes some compounds to oxidize, ruining flavor, function, or stability. Sealing mixtures in airtight containers, sometimes with food-safe desiccant packets, keeps moisture and oxygen out.

Container Choice Isn't Just About Size

Glass, stainless steel, high-quality plastics—each plays a role. Glass keeps flavors steady, doesn’t leach chemicals, and lets you watch for changes. Stainless steel wipes clean and survives temperature swings. Some plastics release compounds over time or let through air and moisture. Not every home or facility will buy glass jars for everything, but switching anything sensitive out of soft, squeezable plastic pays off.

Labeling: The Overlooked Tool

Labels don’t just help you spot a chili powder mix from an oatmeal blend. Good labels track "mixed on" and "best by" dates. Skipping this step leads to guessing games, wasted ingredients, and riskier outcomes. In food, accurate tracking cuts down on both spoilage and the chance of someone using an out-of-date mix.

Simple Steps That Last

Every year, the FDA and other quality control bodies release recalls on products linked to improper storage. No need to get fancy. Aim for consistent, cool storage. Keep light and air out. Use the right containers. Make solid labels. Time shows that these habits pay off, not just in safety, but in fewer lost batches. The up-front effort stays small compared to the savings and reliability you get in return.

Is this product suitable for use in rubber compounding or tire manufacturing?

Looking Closer at Material Choice

Choosing the right ingredient for tire production is a decision that stretches beyond cost. Over the years, I learned that what gets mixed into rubber defines more than just performance—it shapes safety, durability, and environmental impact. A product isn’t simply tossed into a mixer and forgotten. Every addition reacts with heat, pressure, and other chemicals in ways that ripple through the finished tire’s longevity and grip. People’s lives rest on these decisions, especially on wet roads at high speeds.

Real-World Needs Drive the Conversation

Factories don’t run in a vacuum. Workers on the line notice if a batch behaves differently. During my time consulting with a tire company, we ran side-by-side tests with alternative fillers. Even small changes altered viscosity, causing headaches for the mixer operators. It’s not just about lab numbers; it’s about whether teams can handle the product day in, day out. If handling required new methods—like extra temperature controls or more protective gear—that carried real costs.

Health and Environmental Responsibility

People now watch closely for toxic substances. Regulations got stricter, and public trust wavered if companies dodged them. One case comes to mind where a plant in Asia tried cheapening its mix with unvetted powders, leading to hazardous dust that caused complaints and fines. Safe, clean ingredients cut down on problems down the line, and that trust outlasts a small savings in raw materials. Reliable sources and full traceability matter more than ever.

Performance on the Road

On the technical front, it’s easy to get dazzled by claims of improved abrasion resistance or better flexibility. Those claims only count if the product holds up in the palm of your hand and out on the street. Road tests uncovered that some so-called breakthroughs made wet grip worse or led to quicker wear—not always visible in a lab under controlled cycles. Wear and tear shape public opinion quickly. Drivers remember tires that last and keep families safe in the rain.

Learning from Setbacks

Some years ago, a supplier promised that an experimental resin would boost tensile strength and cut cost. We learned too late that this came at the expense of rolling resistance, leading to higher fuel use for drivers. In a business where fleets compare every kilometer, that trade-off wasn’t worth it. I realized then how every ingredient, down to trace additives, pulls its own weight—not just at the start but over the tire’s whole life.

Building Trust and Solutions

Open lines with suppliers, thorough vetting, and repeated batch testing offer the strongest way forward. Instead of chasing the newest ingredient, leaning into long-term partnerships leads to fewer headaches. Producers should share independent test results and show willingness to make samples available for real production runs. Including feedback from the shop floor and the end customer builds a picture that numbers alone can’t fill in.

What is the recommended method for mixing or dispersing this product in formulations?

Getting Ingredients to Blend in the Real World

Plenty of instruction manuals make mixing sound easy. Just toss in the ingredient, give it a swirl, and you’ll end up with a perfect product. In the lab or in a small kitchen, that sometimes works. Once scaling up for real-life production, it gets trickier. I’ve seen people dump powders straight into a cold liquid batch, hoping for the best. More often than not, clumps form and you lose material stuck to the sides of the tank. You wind up chasing lumps with a stick blender, wasting both time and money.

Right Order, Right Tools

Order matters. I always start by checking if the powder prefers to be dispersed in oil or water. That comes from understanding the chemistry behind the ingredient, and talking with people who’ve mixed a similar product before. Sometimes the supplier offers tips on pre-wetting the powder with a small amount of compatible oil. This step helps keep things from sticking together right from the start.

Equipment makes all the difference. In my experience, overhead stirrers with good shear blades push ingredients out of their comfort zone and into something you can actually use. Blade speed, batch size, and powder particle size all decide how long you’ll be standing there. High-shear mixers, like the Silverson or Ultra-Turrax, don’t just move product—they tear apart agglomerates, helping the active ingredient break loose and blend properly. Homogenizers take things even further if the process needs it.

The Value of Temperature and Patience

I never skip checking the temperature needs. Certain emulsifiers and gums dissolve better in water at 60–70°C. Cold mixing can work if the ingredient tolerates it, but sometimes mild heat opens up the particles, allowing even hydration. Rushing the process causes more headaches than waiting that extra few minutes. Investing time upfront beats spending hours later fishing out undissolved chunks.

Additives Can Lend a Hand

Some powders just refuse to play nice. In those cases, a little help from dispersing aids—like polysorbates or glycols—makes a drastic difference. These helpers "wet" the particle surfaces so they’re less likely to clump together. For stubborn clays or gums, I’ve used a trick called “pre-mixing” in a small amount of the carrier liquid, then adding the smooth slurry into the rest of the batch. This shortcut keeps both frustration and batch failures low.

Testing Small Saves Costly Mistakes

Scaling a process from beaker to production vat isn’t as simple as multiplying quantities. I always run a pilot batch before anything goes industrial. Even a five-liter test run can reveal surprises—unexpected thickening, foam, or separation problems show up here instead of ruining a full-scale batch. Quality control at this stage protects both the final customer and the reputation you’ve worked hard to build.

Listening to Experience—and Science

Mixing turns into problem-solving. I pay attention to the stories from seasoned operators and chemists, learning what’s gone wrong before. Mistakes cost money, so asking questions upfront saves resources. Scientific data, such as particle size analysis and solubility measurements, back up choices about process tweaks. It’s a blend of theory and hands-on knowledge that brings reliable results.

Final Thoughts on Smarter Mixing

The best advice I’ve taken for mixing and dispersing? Don’t skip learning from others who’ve done it before. Trust the right tools, put the ingredient in at the right time, and don’t be afraid to change method if clumps or separation show up. Every batch teaches something new. Efficiency and product quality both improve when every variable—from powder type to blade speed—gets the attention it deserves.

Mixture Of Bis[3-(Triethoxysilyl)Propyl]Disulfide (50%) And Carbon Black (50%)
Mixture Of Bis[3-(Triethoxysilyl)Propyl]Disulfide (50%) And Carbon Black (50%)
Names
Preferred IUPAC name Mixture of [3-(triethoxysilyl)propyl] disulfide and carbon black
Other names TESPT carbon black mixture
Bis[3-(triethoxysilyl)propyl]disulfide/carbon black blend
Mixture of TESPT and carbon black
Silane-coupling agent/black blend
Disulfide silane-carbon black mixture
Pronunciation /ˈmɪks.tʃər ʌv bɪs θriː traɪˌiːˌθɒk.siˈsaɪ.lɪl ˈprəʊ.pɪl daɪˈsʌl.faɪd fɪf.ti ænd ˈkɑː.bən blæk fɪf.ti/
Identifiers
CAS Number 112945-12-3
Beilstein Reference 697425
ChEBI CHEBI:131529
ChEMBL CHEMBL1851494
ChemSpider 25726640
DrugBank DB14005
ECHA InfoCard 17b9c7b7-7763-4e36-a38f-42464344e813
EC Number 412-040-1
Gmelin Reference 56773
KEGG C19607
MeSH D017157
PubChem CID 129701088
RTECS number WS4250000
UNII J9PT9FH74D
UN number UN3077
CompTox Dashboard (EPA) DTXSID3020377
Properties
Chemical formula C18H42O6S2Si2 + C
Molar mass 391.66 g/mol
Appearance Black powder
Odor Characteristic
Density 0.990 g/cm3
Solubility in water Insoluble
log P -0.3
Magnetic susceptibility (χ) -7.56e-6 cm³/mol
Refractive index (nD) 1.480
Viscosity 30000 mPa.s
Dipole moment 8.01 D
Thermochemistry
Std molar entropy (S⦵298) 208 J·mol⁻¹·K⁻¹
Pharmacology
ATC code A03333201682
Hazards
Main hazards Causes serious eye irritation. May cause an allergic skin reaction. Suspected of causing cancer. Toxic to aquatic life with long lasting effects.
GHS labelling GHS02, GHS07, GHS08
Pictograms GHS07,GHS08
Signal word Warning
Hazard statements H317, H319, H335, H351, H373
Precautionary statements P260, P261, P264, P270, P271, P272, P273, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P333+P313, P362+P364, P403+P233, P405, P501
NFPA 704 (fire diamond) 2-1-1 Health:2 Flammability:1 Instability:1
Flash point > 200 °C (Closed cup)
Autoignition temperature > 343 °C (649 °F)
LD50 (median dose) LD50 (median dose): > 2000 mg/kg (rat, oral)
PEL (Permissible) Not established
REL (Recommended) 5 mg/m³
Related compounds
Related compounds Bis[3-(triethoxysilyl)propyl]disulfide
Carbon black
Silane coupling agents
3-(Triethoxysilyl)propyl mercaptan
Bis[3-(trimethoxysilyl)propyl]disulfide