Alchemist Worldwide Ltd

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Material Safety Data Sheet: N-Hexadecylmethyldichlorosilane

1. Identification

Product Name: N-Hexadecylmethyldichlorosilane
Chemical Formula: C17H36Cl2Si
Synonyms: Dichloro(methyl)hexadecylsilane
Recommended Use: Surface treatment agent, coupling agent in advanced chemical syntheses, hydrophobic coatings for laboratory glassware and scientific equipment
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CAS Number: 18719-76-1

2. Hazard Identification

Classification: Corrosive to skin and eyes, irritating to respiratory tract, hazardous to aquatic environments
GHS Label Elements: Danger symbol (Corrosive, Irritant)
Signal Word: Danger
Hazard Statements: Causes severe burns to skin and eyes, produces harmful fumes that may irritate throat and lungs if inhaled, harmful if swallowed, possible lung injury from inhalation of vapors
Precautionary Statements: Use protective gear, avoid breathing vapors or aerosols, do not handle without proper training, wash exposed skin thoroughly after contact, store away from water sources

3. Composition / Information on Ingredients

Main Ingredient: N-Hexadecylmethyldichlorosilane     Concentration: >95%
Impurities/Other Components: Chlorosilanes (trace amounts), hydrocarbons (negligible amounts), no identified carcinogens present

4. First Aid Measures

Inhalation: Move person to fresh air immediately, keep calm, administer artificial respiration if breathing stops, seek medical attention promptly
Skin Contact: Rinse affected area under running water for at least 15-20 minutes, remove contaminated clothing and shoes, do not delay medical examination
Eye Contact: Rinse eyes with a continuous gentle stream of water for at least 15-20 minutes, hold eyelids open, consult an ophthalmologist right away
Ingestion: Rinse mouth thoroughly, do not induce vomiting, drink plenty of water if person is conscious, seek hospital care as soon as possible
Indications for Immediate Medical Attention: Chemical burns, difficulty breathing, persistent irritation, delayed lung injury

5. Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical powder, carbon dioxide (CO2), foam
Unsuitable Media: Water (may react to produce hydrogen chloride and flammable gases)
Special Hazards: Releases hydrochloric acid, silicon oxides, and combustible vapors under fire conditions
Protective Equipment: Self-contained breathing apparatus, full protective fire gear
Specific Firefighting Methods: Contain runoff, avoid contact with water while extinguishing, approach from upwind to avoid toxic gases, cool containers with dry methods

6. Accidental Release Measures

Personal Precautions: Wear chemical splash goggles, gloves, lab coat, and appropriate respirator, keep unprotected persons away from spill area
Environmental Precautions: Prevent entry into drains, sewers, or rivers, contain spillage with inert absorbent like dry sand or earth
Cleanup Methods: Scoop up using non-sparking tools, absorb residue with sand or suitable absorbent, place in labeled chemical waste container, ventilate affected area thoroughly, wash down contaminated surfaces avoiding water contact with chemical
Emergency Procedures: Notify local authorities if large quantities enter water or soil, evacuate non-essential personnel

7. Handling and Storage

Safe Handling Recommendations: Work in well-ventilated chemical fume hood, do not breathe vapors, avoid direct contact with material, keep containers tightly closed
Hygiene Practices: Wash hands and forearms after handling, restrict eating/drinking/smoking in work areas, decontaminate protective gear before reuse
Storage Conditions: Store in dry, cool, corrosion-resistant area away from incompatible substances, including water, alcohols, strong bases and oxidizers, protect from sunlight and moisture, use secondary containment
Incompatibles: Strong acids, water, alcohols, oxidizing agents, bases

8. Exposure Controls and Personal Protection

Exposure Limits: No established occupational exposure limits for this substance, limit exposure as low as reasonably achievable
Ventilation: Local exhaust recommended, maintain low concentration vapors in workplace
Personal Protection: Chemical-resistant gloves (nitrile or neoprene), splash-proof goggles or face shield, lab coat or apron, closed-toe shoes, respiratory protection (half-mask with acid gas cartridge or supplied air system for large spills)
Engineering Controls: Eyewash station and emergency safety shower in immediate work area, chemical-resistant countertops and flooring material

9. Physical and Chemical Properties

Appearance: Clear, colorless to pale yellow liquid
Odor: Slight chlorine odor, may be irritating to nose
Molecular Weight: 339.47 g/mol
Boiling Point: Approx. 134 °C at 0.7 mmHg
Melting Point: Not precisely established; substance remains liquid at room temperature
Solubility: Reacts violently with water, insoluble in water, soluble in organic solvents (chloroform, toluene, hexane)
Vapor Pressure: Low at 20°C
Density: About 0.90 – 0.93 g/cm3 at 20°C
pH: Not applicable (undergoes hydrolysis in water)
Flash Point: >80°C (closed cup)

10. Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions, decomposes in presence of moisture
Reactivity: Vigorous reaction with water generating HCl gas, reacts with alcohols, amines, and strong oxidizing agents
Conditions to Avoid: Contact with moisture, exposure to air, direct sunlight, contamination with incompatible materials
Decomposition Products: Hydrogen chloride, methyl hexadecyl silanols, silicon oxides

11. Toxicological Information

Acute Toxicity: Harmful if swallowed or inhaled, causes severe tissue burns to oral, nasal, and respiratory passages
Skin Corrosion/Irritation: Causes deep burns and blisters on contact, possible delayed onset of symptoms
Eye Damage/Irritation: Immediate pain, redness, possible tissue destruction, risk of permanent damage or loss of vision
Respiratory Sensitization: Prolonged exposure can result in respiratory irritation or chemical pneumonitis
Carcinogenicity, Mutagenicity, Reproductive Effects: No data available; not classified as carcinogenic by major agencies
Long-Term Effects: Scar tissue formation, persistent respiratory or skin issues after acute exposure

12. Ecological Information

Acute Aquatic Toxicity: Toxic to aquatic organisms, may cause long-lasting effects in aquatic environments
Persistence and Degradability: Undergoes slow hydrolysis in soil and waterways, resulting byproducts may accumulate
Bioaccumulation: Low potential for bioaccumulation in animal tissues
Mobility: Strongly adsorbed to soil, low movement through groundwater if uncontaminated by spill
Avoid Release: Do not allow entry to drains, soil, surface water or groundwater, notify environmental authorities in event of accidental large release

13. Disposal Considerations

Waste Disposal: Collect liquid and absorbent in sealed, labeled chemical waste containers, store safely until disposal through licensed hazardous waste contractor
Disposal Methods: Preferred incineration in a chemical incinerator equipped to handle halogenated waste, accompanied by scrubbing system for gases
Contaminated Packaging: Rinse thoroughly with compatible solvent, collect all rinsate as hazardous waste, dispose in accordance with federal and local regulations
Regulatory Compliance: Dispose subject to hazardous waste regulations, never release into sewers or natural water sources

14. Transport Information

UN Number: 1760
Proper Shipping Name: Corrosive liquids, n.o.s. (contains n-hexadecylmethyldichlorosilane)
Hazard Class: 8 (Corrosive)
Packing Group: II
Labels: Corrosive
Special Transport Precautions: Keep containers upright and secured, segregate from incompatible goods during transport, protect containers from moisture and rough handling, consult all local and international shipping regulations before consignment

15. Regulatory Information

Chemical Inventories: Listed on relevant chemical substance inventory lists in major jurisdictions if imported or produced in significant quantity
OSHA Hazards: Classified as corrosive, needs hazard communication standards compliance
SARA Title III: Not listed as extremely hazardous, not subject to specific threshold reporting
DSL/NDSL (Canada): Consult local regulations for status
EU Classification: Corrosive (C), Hazard Symbols: C
Other Regulations: Product falls within local, regional, and global workplace safety acts; proper labeling, storage, and employee training required
Safety Assessment: Facilities working with this product follow strict control, monitoring, and emergency response plans, updated in accordance with legal and industry standards