Alchemist Worldwide Ltd

Conhecimento

MSDS for N,N-Diethylaminopropyltrimethoxysilane

Identification

Product Name: N,N-Diethylaminopropyltrimethoxysilane
Chemical Formula: C10H25NO3Si
Synonyms: 3-(Diethylamino)propyltrimethoxysilane
CAS Number: 41051-80-3
Recommended Use: Silane coupling agent, adhesion promoter, surface modifier
Supplier Details: Chemical manufacturer or distributor, with emergency contact number provided on label

Hazard Identification

Classification: Flammable liquid (Category 3), Skin irritant (Category 2), Eye irritant (Category 2A), Acute toxicity, oral (Category 4)
Hazard Statements: Flammable liquid and vapor. Causes skin irritation. Causes serious eye irritation. May be harmful if swallowed.
Pictograms: Flame, Exclamation Mark
Signal Word: Warning
Precautionary Statements: Keep away from heat and open flames. Avoid breathing vapors. Wear gloves and eye protection. Wash hands thoroughly after handling. If in eyes, rinse cautiously with water.

Composition / Information on Ingredients

Chemical Name: N,N-Diethylaminopropyltrimethoxysilane
Concentration: 95-100%
Impurities: Methanol as trace hydrolysis byproduct, known for minor impact during handling, below safety thresholds
Other Ingredients: None present above reporting limits

First Aid Measures

Inhalation: Move person to fresh air if signs of breathing difficulty appear. Seek medical attention for persistent cough or shortness of breath.
Skin Contact: Remove contaminated clothing. Wash affected areas thoroughly with soap and water. Treat persistent skin irritation with medical attention.
Eye Contact: Flush eyes gently with lukewarm water for at least 15 minutes, keeping eyelids lifted. Immediately call for medical help if irritation persists.
Ingestion: Rinse mouth. Do not induce vomiting unless directed by medical personnel. Provide water only if person is fully conscious. Seek immediate medical attention.

Fire-Fighting Measures

Suitable Extinguishing Agents: Use alcohol-resistant foam, carbon dioxide, or dry chemical powder. Steer clear of using direct water streams on burning liquid.
Special Hazards: Combustion releases toxic fumes, including oxides of carbon, nitrogen, and silicon compounds.
Protective Equipment: Firefighters require self-contained breathing apparatus and chemical-resistant gear. Remove non-involved individuals from danger zone.
Explosion Risk: Vapors may form explosive mixtures with air above flash point of 60°C (140°F). Cool containers near fire with water spray to prevent pressure build-up and rupture.

Accidental Release Measures

Personal Precautions: Ventilate area. Eliminate sources of ignition. Don chemical splash goggles, gloves, and lab coat or apron.
Environmental Precautions: Prevent spillage from entering drains, soil, or surface waters.
Cleanup Methods: Absorb liquid using inert material such as sand or diatomite. Collect and dispose of in chemical waste container. Wash surfaces thoroughly with detergent and water following cleanup.

Handling and Storage

Handling: Use only in well-ventilated settings. Avoid exposure to heat, flames, and sparks. Keep containers tightly sealed during transfer and storage. Avoid contact with skin and eyes.
Storage: Store in original container in a cool, dry location away from incompatible substances like oxidizers or water. Isolate from sources of ignition. Label containers clearly with hazard information. Maintain storage area ventilation.

Exposure Controls and Personal Protection

Engineering Controls: Employ local exhaust or general ventilation to keep vapor concentrations below threshold limits.
Personal Protective Equipment: Wear butyl rubber or nitrile gloves, splash-proof chemical goggles, and flame-resistant lab coat. In case of high vapor concentrations, use NIOSH-approved organic vapor respirator.
Hygiene Measures: Wash hands before breaks and after work. Do not eat, drink, or smoke when handling chemicals. Remove contaminated clothing promptly and wash before reuse.

Physical and Chemical Properties

Appearance: Colorless to pale yellow transparent liquid
Odor: Amine-like odor
Melting Point/Range: Not available
Boiling Point: 255°C (491°F)
Flash Point: 78°C (172°F) closed cup
Vapor Pressure: 0.2 mmHg at 25°C
Solubility: Hydrolyzes in water, soluble in organic solvents
Density: About 0.94 g/cm³ at 25°C
pH: Not determined
Viscosity: 2-4 mPa·s at 25°C
Partition coefficient: n-Octanol/water: No data available
Decomposition Temperature: Unknown

Stability and Reactivity

Chemical Stability: Stable under standard conditions with sealed packaging. Susceptible to hydrolysis in moisture.
Reactive With: Strong oxidizers, acids, water, and alcohols produce methanol.
Hazardous Decomposition Products: Produces nitrogen oxides, carbon oxides, and silicon oxides on burning.
Polymerization: Does not polymerize under normal conditions.

Toxicological Information

Acute Toxicity: May cause moderate irritation to respiratory tract, skin, and eyes.
Skin Sensitization: Prolonged skin contact increases chances of dermatitis or chemical burns.
Inhalation: High vapor concentrations can produce dizziness, headache, and drowsiness.
Ingestion: Swallowing causes nausea, abdominal discomfort, or more serious effects if large quantities are taken.
Chronic Effects: No prolonged systemic toxicity in reported cases, but repeated exposure enhances skin risk.
Carcinogenicity: None classified for this chemical by major regulatory agencies.

Ecological Information

Ecotoxicity: Low predicted toxicity to aquatic organisms, but breakdown products—especially methanol—impact water life.
Mobility: Hydrolysis products readily dilute into moisture environments and migrate through soil.
Persistence and Degradability: Silane structure hydrolyzes quickly; environmental breakdown occurs within days.
Bioaccumulation: Compound shows little tendency to accumulate in organisms.
Other Adverse Effects: Prevent bulk quantities from entering water systems.

Disposal Considerations

Waste Handling: Collect contaminated absorbents, soil, or debris and containerize for hazardous waste disposal.
Disposal Methods: Incinerate or dispose of using facilities that follow local environmental regulations. Do not drain into sewer.
EU Waste Code: 07 02 99 or suitable based on chemical inventory.

Transport Information

UN Number: 1993
Proper Shipping Name: Flammable liquid, n.o.s. (N,N-Diethylaminopropyltrimethoxysilane)
Transport Hazard Class: 3 (flammable liquid)
Packing Group: III
Environmental Hazards: Not classified as marine pollutant
Special Precautions for User: Avoid loading with strong acids, bases, or oxidizers; label bottles; keep upright during transport.

Regulatory Information

Workplace Regulation: OSHA, ACGIH, and European Directives set exposure limits for volatile amines and solvents.
EPA Status: Subject to reporting for certain releases under TSCA.
EU Classification: Flammable liquid, skin and eye irritant under CLP.
Labeling: Follows GHS conventions: flame and exclamation hazard pictograms, warning signal word on all containers.
Inventory Lists: Listed on TSCA, EINECS/ELINCS, and international chemical control regulations.